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Peel the pears or leave part of the skin on for a rustic look. Halve them or leave them whole and remove the core with a melon baller.
Slice the lemon and scrape the seeds from the vanilla pod.
Place the pears together with the lemon slices, vanilla seeds, and cinnamon stick in a large stew pot. Add the water and cane sugar.
Bring the mixture to a boil and let it simmer gently:
For cooking pears: about 20 minutes
For softer pear varieties: about 10 minutes
Remove the pears from the syrup and let them cool. They are now ready to use!
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